鄂西黄陵隆起东缘鄂宜页2井五峰组—龙马溪组页岩气储层特征与含气性          下载免费PDF全文

张保民  蔡全升  陈孝红  王传尚  张国涛  陈林  李培军  李炎桂 《中国地质》2021,48(5):1485-1498

鄂西地区五峰组-龙马溪组已成为中国南方页岩气勘探的热点领域。为深化该区页岩储层及含气性特征认识,本文以鄂宜页2井钻井及测试分析资料为基础,以笔石带为标尺,对五峰组-龙马溪组下部黑色富有机质页岩的岩石学特征、有机地化特征、储集空间类型及结构特征进行深入研究,分析总结了页岩储层含气性特征及影响因素,并对页岩储层开展了综合评价。结果表明：鄂宜页2井五峰组-龙马溪组下部黑色岩系缺失LM5-LM6笔石带,富有机质页岩上延至LM7笔石带,总厚度约16 m;岩性以硅质页岩夹少量硅质岩、混合质页岩和黏土质页岩为主,有机质类型为Ⅰ-Ⅱ1型,Ro为1.88%~2.03%,显示黑色页岩已过大量生气阶段;页岩储集空间主要为小于100 nm的有机质纳米孔、直径大于5 μm的微米孔和构造微裂缝,其中纳米孔占比超过50%,孔隙容积、比表面积与有机碳含量存在显著正相关性;现场解析总含气量为0.068~3.33 m³/t,平均1.13 m³/t,高含气量段集中于凯迪阶WF2-WF3与鲁丹阶LM2-LM4,含气量与TOC、脆性矿物含量之间具有明显的正相关性;根据TOC、含气性、脆性矿物含量以及页岩沉积环境等参数进行综合评价,Ⅰ类储层主要对应于凯迪阶WF2-WF3笔石带以及鲁丹阶LM2-LM4笔石带以深水环境下形成的硅质页岩和硅质岩层段,总厚度约9 m,是该区五峰-龙马溪组水平钻井的最佳甜点段。  相似文献   

湖南川口岩体型钨矿赋矿花岗岩地球化学特征及LA-ICP-MS锆石U-Pb定年          下载免费PDF全文

蔡富成  秦锦华  覃金宁  姜必广  朱成生 《中国地质》2021,48(4):1212-1224

川口矿田钨矿床产于湖南衡阳川口岩体的外接触带及岩体内部,矿床类型主要有岩浆热液石英细脉带型和石英大脉型。近年川口矿田取得了重大找矿突破,并发现了新类型的岩体型钨矿。本文对川口岩体型钨矿床的黑云母二长花岗岩及赋矿的白云母二长花岗岩分别进行了 LA-ICP-MS锆石U-Pb定年和岩石地球化学特征研究,获得川口岩体的成岩年龄为(223.1 ± 0.78)Ma,MSWD=0.98,n=24,岩体型钨矿成矿年龄为(224.6±1.31)Ma,MSWD=0.33,n=9,为印支期成岩成矿。川口花岗岩具有高SiO_2,富K_2O+Na_2O,低CaO、MgO的特点,属于过铝质高钾钙碱性系列S型花岗岩,形成于碰撞环境下弱挤压构造体制。川口岩体稀土总量(∑REE)整体较低,轻稀土相对较富集,具有强烈的负Eu异常,富集大离子亲石元素Ba、K和高场强元素Ta,而亏损大离子亲石元素Sr和相容元素P、Ti等,表明该岩体各阶段花岗岩来自同一岩浆源,且经历了高度演化。赋矿花岗岩更低的δEu值及(La/Yb)_N值,表明其结晶分异程度更高。  相似文献   

滇东北DD1井五峰组—龙马溪组地层界线划分及沉积环境演变          下载免费PDF全文

冯伟明  李嵘  赵瞻  余谦  杨瀚  谢渊  叶定南 《中国地质》2021,48(1):297-308

DD1井上奥陶统临湘组泥灰岩之上发育大套粉砂质泥岩,笔石化石缺乏,也未发现观音桥段含赫南特贝灰岩标志层,O-S界线通过生物地层和岩石地层方法难以确定。微量、稀土元素分析表明,粉砂质泥岩中部(1288.3 m)的Th、Sr、Y、Th/U以及Cen、Eun、δCe、δEu曲线均呈现尖锐的异常峰,该处ΣREE含量显著高于上下地层,REE分布曲线右倾斜率更大。将DD1井与扬子地区其他O-S界线剖面的元素地球化学特征进行对比分析,可判断DD1井存在五峰组观音桥段,该标志层的厚度也小于1 m。微量元素地球化学氧化-还原判别图还表明,五峰期—龙马溪期早期沉积水介质主要处于弱氧化环境,观音桥期氧化性达到最强;根据沉积学标志分析,O-S之交沉积相演变过程为:潮下→潮间→潮上→潮间,在观音桥期水体最浅,为潮上带沉积。  相似文献   

鲁西归来庄金矿床矿化闪长玢岩锆石U-Pb年龄          下载免费PDF全文

李世勇  李杰  蒋雷  宋明春  宋英昕  张英梅 《中国地质》2021,48(1):334-336

1研究目的(Objective)归来庄金矿床是鲁西地区最大的金矿床,具有独特的金碲矿化特征,其大地构造位置处于华北板块东缘之鲁西隆起区,著名的郯庐断裂带西侧(图1a)。矿体主要赋存于萤石化隐爆角砾岩和碳酸盐岩(寒武系和奥陶系白云岩、石灰岩)中,受NNW向区域性燕甘断裂的近EW向次级断裂控制(图1b)。矿床成因类型被认为是中低温热液隐爆角砾岩型,与早侏罗世的中偏碱性次火山杂岩体-铜石岩体密切相关。以往勘查研究表明,在闪长玢岩中并未发现工业矿体。本次在矿床深部勘查的基础上,对矿床深部矿化情况作了详细研究,新发现了闪长玢岩脉型金矿体(图1c、d),测试了含矿闪长玢岩的锆石U-Pb年龄,以此来限定成矿年龄的上限。  相似文献   

思茅地块西缘大凹子组地层序列及地质时代          下载免费PDF全文

魏月华  甘正勤  刘桂春  冯庆来 《地球科学》2021,46(2):418-431

目前关于思茅地块西缘大凹子组的形成时代仍有分歧.在思茅地块西缘大中河剖面采集了硅质岩、砂岩、凝灰岩和玄武岩,通过放射虫组合和锆石U-Pb年龄方法,厘定其地质时代,并结合区域资料恢复地层序列.通过详细剖面实测,发现该剖面由6个地层断片组成:第一、四断片以含放射虫硅质岩为特征,放射虫组合指示其时代为晚泥盆世至早石炭世早期;第二、五断片以火山碎屑岩、具有鲍玛序列沉积特征的火山碎屑沉积岩为主,锆石U-Pb同位素年龄指示其时代为志留纪中期至早泥盆世;第三、六断片以火山岩沉积为特征,锆石U-Pb同位素年龄指示其时代为志留纪早期.结合前人资料认为思茅地块西缘分布的海相火山岩、碎屑岩和含放射虫硅质岩地层层序代表了志留纪到早石炭世早期的岛弧火山-沉积地层序列.   相似文献   

南秦岭东部新元古代埃达克质岩的发现及其地质意义     

蔡文春  曾忠诚  赵鹏彬  杨宗永  李景晨  王明志  朱雪丽  张小明 《地质学报》2021,95(3):686-702

秦岭造山带是一条复合型大陆碰撞造山带,存在若干新元古代构造岩浆事件的遗迹,它们对深化认识南北秦岭汇聚-碰撞过程和Rodinia超大陆聚合具有重要意义。本文对南秦岭东部豆腐尖岩体英云闪长岩开展LA-ICP-MS锆石U-Pb年代学和全岩主微量元素地球化学研究。代表性样品的²⁰⁶Pb/²³⁸U加权平均年龄为860.7±6.0Ma,表明其形成时代为新元古代。岩石地球化学特征表现为高SiO₂(62.41%-68.89%)、高Al₂O₃(15.33%-17.33%),富Na₂O(4.23%-5.80%)和高Na₂O/K₂O比值(1.11-2.41),富Sr(>400×10^-6),低MgO(0.55%-2.08%),低Y(7.40×10^-6-18.20×10^-6)、Yb(0.63×10^-6-1.62×10^-6),高Sr/Y比值(31.49-78.22),轻稀土元素显著富集[(La/Yb)_N>20],弱Eu正异常,具埃达克质岩特征。较高的K₂O含量(2.00%-4.31%)和低MgO以及显著的高La/Yb比值等特征指示,其具有典型高钾钙碱性埃达克质岩特征,很可能源于加厚下地壳的部分熔融,推测该岩体形成时南秦岭地壳厚度可能达到65 km。结合区域地质资料,认为豆腐尖岩体形成于陆-陆碰撞环境,是新元古代松树沟洋盆闭合后北秦岭和南秦岭碰撞造山的产物,是Rodinia超大陆聚合事件在该地区的岩浆响应。新元古代早期商南豆腐尖高钾钙碱性埃达克质岩的首次识别为限定南-北秦岭碰撞事件提供了有力约束。  相似文献   

Rb–Sr dating of sulfides and S–Pb isotopic study of the Bayanbaolege Ag polymetallic deposit,Inner Mongolia,NE China     

《Chemie der Erde / Geochemistry》2021,81(1):125724

The large-scale Bayanbaolege Ag polymetallic deposit is situated in the Tuquan–Linxi Fe-Sn-Cu-Pb-Zn-Ag metallogenic sub-belt in eastern slopes of the southern Great Xing’an Range, NE China. The sulfide-quartz vein-type orebodies in the deposit are hosted primarily in the Early Cretaceous granodiorite porphyry and Late Permian strata. Three primary paragenetic stages of veining have been identified: (I) arsenopyrite- pyrite-quartz stage, (II) pyrite-sphalerite-quartz stage, and (III) galena-silver minerals (pyrargyrite, argentite, and pearceite)-calcite stage. The Rb–Sr dating of sulfides yielded an isochron age of 129.9 ± 2.9 Ma (MSWD = 2.1) for the sphalerite, which constrains the mineralization age to the Early Cretaceous. Rb and Sr concentrations in the sulfides ranged from 0.0940 to 1.0294 ppm and 0.0950–3.3818 ppm, respectively. The initial ⁸⁷Sr/⁸⁶Sr value of the sphalerite was 0.70852 ± 0.00018, indicating that the mineralized materials were derived from the mixed crust-mantle source area. S isotope analysis showed that the δ³⁴S values of the sulfide samples varied in a narrow range, from −1.5‰ to +1.3‰ (mean −0.65‰), indicating a magmatic S source. Pb isotopic ratios of the sulfides (²⁰⁶Pb/²⁰⁴Pb = 18.306–18.416, ²⁰⁷Pb/²⁰⁴Pb = 15.524–15.605, ²⁰⁸Pb/²⁰⁴Pb = 38.095–38.479) and the granodiorite porphyry (²⁰⁶Pb/²⁰⁴Pb = 18.341–18.933, ²⁰⁷Pb/²⁰⁴Pb = 15.539–15.600, ²⁰⁸Pb/²⁰⁴Pb = 38.134–38.944) reflect that the ore-forming materials originated from contemporaneous magma with Early Cretaceous granodiorite porphyry. This study of the Bayanbaolege deposit and other hydrothermal deposits in the area provides compelling evidence that the widespread Mesozoic magmatism and mineralization in the southern Great Xing’an Range occurred in an intracontinental extensional tectonic setting, which was associated with the westward subduction of the paleo-Pacific plate.  相似文献   

柴达木盆地一里坪盐湖富锂卤水特征、储层物性及富水区分析     

赵艳军  焦鹏程  汪明泉  张大义  朱振光  胡宇飞 《地质学报》2021,95(7):2062-2072

一里坪盐湖是柴达木盆地中一个典型的富锂卤水矿床,具有重大的经济价值.本文以查明盐湖深部卤水分布为目的,从卤水储层的空间分布特征和储层物性的角度对富水区进行预测,为卤水开发提供依据.研究区位于一里坪成盐盆地沉积中心区域,晚更新世末期以来,以沉积浅湖相的含淤泥和黏土粉砂岩,盐湖相的含粉砂和黏土的石盐岩为特征.在垂向上,由上下两套石盐岩夹中部粉砂岩组成一里坪富锂卤水的储层;平面上,研究区北部主要为浅湖相,往南过渡为盐湖相,石盐岩厚度在东南部最大.对储层厚度、孔隙度和给水度的分析表明,第Ⅱ矿层孔隙型和晶间型卤水优质储层均位于研究区东部,可作为卤水资源勘查开采的重点区域.  相似文献   

Geochronology and geochemical properties of the large-scale graphite mineralization associated with the Huangyangshan alkaline pluton,Eastern Junggar,Xinjiang, NW China     

《Chemie der Erde / Geochemistry》2021,81(4):125820

The Huangyangshan alkaline pluton is located within the southern part of the Eastern Junggar orogenic belt in Xinjiang Province, and forms part of the Kalamaili alkaline granite belt. The pluton hosts the Huangyangshan super-large graphite deposit, which develops unique spherical structure and coexists with metal sulfides. This study examines the genetic relationship between the alkaline magmatism that formed the pluton and the graphite mineralization using zircon LA–ICP–MS U–Pb dating, geochemical analysis for representative rock types in the Huangyangshan pluton, and new Re–Os isotope dating for the graphite in the Huangyangshan graphite deposit. Zircons from medium-grained arfvedsonite granite, medium–fine-grained amphibole granite, medium-grained biotite granite, and fine-grained biotite granite phases of the Huangyangshan pluton yield weighted mean U–Pb ages of 322.7 ± 4.5, 318.3 ± 4.0, 303.9 ± 2.1, and 301.1 ± 3.6 Ma, respectively, indicating that all of the granite phases were emplaced during the Late Carboniferous over a period of around 20 Myr. Six graphite samples from the deposit yield a Re–Os isochron age of 332 ± 53 Ma. Combining these ages with the genetic relationship between the graphite mineralization and magmatism in the study area and the relatively large uncertainty on the Re–Os isochron age for the graphite suggests that the mineralization formed at ca. 320 Ma. The graphite samples yield an initial ¹⁸⁷Os/¹⁸⁸Os value of 0.38 ± 0.2, indicative of carbon derived from a mixture of organic and mantle-derived sources. The different granite phases in the Huangyangshan pluton are geochemically similar with relatively high SiO₂ (75.6–78.2 wt%) and Na₂O + K₂O (8.01–9.04 wt%) and relatively low CaO (0.18–0.7 wt%), MgO (0.06%–0.13 wt%) and Fe₂O₃ (T_Fe2O3 = 1.08–2.06 wt%) contents. The granites are enriched in light rare earth elements (LREE), large-ion lithophile elements (LILEs) (e.g. Rb, Th, and K), and high field strength elements (HFSEs) (e.g. Zr and Hf), depleted in heavy rare earth elements (HREEs), and have negative Ba, Sr, P, Ti, and Eu anomalies. These geochemical characteristics are indicative of derivation from juvenile basaltic oceanic crustal materials in the lower crust. This suggests that the Huangyangshan pluton formed from magmas generated by partial melting caused by mantle-derived magma underplating, with the magmas then undergoing mixing, separation, and significant fractional crystallization. Diorite enclaves within the granites have weaker trace element anomalies that are indicative of magma mixing. In addition, the mantle-derived intermediate–basic end-member involved in the magma mixing is likely one of the important carriers of carbon and metal. In summary, the Late Carboniferous Huangyangshan pluton and its associated graphite mineralization formed in a post-collision extensional tectonic setting in the Kalamaili area.  相似文献   

柴达木盆地一里坪盐湖成盐卤水成分变化及其意义——来自LA- ICP- MS分析石盐流体包裹体组成的证据   总被引：1，自引：0，他引：1  

胡宇飞  汪明泉  赵艳军  焦鹏程 《地质学报》2021,95(7):2109-2120

一里坪盐湖是柴达木盆地一个以富锂卤水为主的干盐湖,蕴藏有丰富的卤水钾锂资源,目前对成矿过程中卤水的成分及其演变规律方面的研究较少.论文选取一里坪盐湖中部钻孔HC2105岩芯的石盐为主要对象,利用激光剥蚀-电感耦合等离子质谱法开展了单个石盐原生流体包裹体成分分析,探讨恢复了一里坪盐湖地区晚更新世以来成盐期的古卤水成分.结果表明,一里坪盐湖下层石盐古卤水Li、B、K等离子浓度均高于上层石盐,这说明晚更新世成矿条件更好.古卤水中Li、B、K和Mg等离子具有正相关性,再结合对Ca离子浓度变化的研究,说明一里坪盐湖的主要物质来源为那棱郭勒河,深部卤水对其物质来源贡献较小;石盐流体包裹体中各离子浓度的演变规律与钻孔沉积韵律以及古气候变化三者基本可以拟合,从而证实盐湖卤水成分变化受到古气候变化的影响,干冷期可能更有利于富锂卤水矿的形成.  相似文献